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• W2150061087 endingPage "2008" @default.
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• W2150061087 abstract "Mesoporous hollow colloidal particles with well-defined characteristics have potential use in many applications. In liquid-phase catalysis, in particular, they can provide a large active surface area, reduced diffusion resistance, improved accessibility to reactants, and excellent dispersity in reaction media. Herein, we report the tailored synthesis of sulfated ZrO2 hollow nanostructures and their catalytic applications in the dehydration of fructose. ZrO2 hollow nanoshells with controllable thickness were first synthesized through a robust sol-gel process. Acidic functional groups were further introduced to the surface of hollow ZrO2 shells by sulfuric acid treatment followed by calcination. The resulting sulfated ZrO2 hollow particles showed advantageous properties for liquid-phase catalysis, such as well-maintained structural integrity, good dispersity, favorable mesoporosity, and a strongly acidic surface. By controlling the synthesis and calcination conditions and optimizing the properties of sulfated ZrO2 hollow shells, we have been able to design superacid catalysts with superior performance in the dehydration of fructose to 5-hydroxymethyfurfural than the solid sulfated ZrO2 nanocatalyst." @default.
• W2150061087 created "2016-06-24" @default.
• W2150061087 creator A5004588741 @default.
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• W2150061087 date "2013-09-10" @default.
• W2150061087 modified "2023-09-26" @default.
• W2150061087 title "A Sulfated ZrO₂Hollow Nanostructure as an Acid Catalyst in the Dehydration of Fructose to 5-Hydroxymethylfurfural" @default.
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• W2150061087 doi "https://doi.org/10.1002/cssc.201300416" @default.
• W2150061087 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24023048" @default.
• W2150061087 hasPublicationYear "2013" @default.
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