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- W2150160900 abstract "The electronic spectra of CuL2 (L = acetylacetonato, benzoyl-acetylacetonato, 3-phenyl-acetylacetonato, dipivaloylmethane) have been treated by the Angular Overlap Method (AOM) and the Crystal Field Theory (CFT). The experimental values of the ligand bite angle (α) and the spin orbit coupling constant (ζ) have been used to solve the 5 × 5 secular determinants for d9 in the double group D2h′, and to find the transition energies. The inclusion of α explicitly in the transition energy expressions brings about a small, non-negligible correction to the calculated spectral parameters, while ζ is important in explaining the observed band intensities and polarizations. The failure of the CFT to explain the electronic spectra of some of the studied complexes is attributed to the need for different CFT parameters for the different type of orbitals involved in the transitions." @default.
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- W2150160900 date "1983-01-01" @default.
- W2150160900 modified "2023-09-25" @default.
- W2150160900 title "Electronic spectra of planar bis-acetylacetonato copper(II) complexes" @default.
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- W2150160900 doi "https://doi.org/10.1016/s0020-1693(00)81701-6" @default.
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