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• W2150463313 abstract "The reaction of benzilmonoxime (BMOH) with CrCl3.6H2O in methanol gives the mono nuclear Cr(III) complex, [Cr(BMO)33 (1). Reaction of complex 1 with a methanolic solution of KOH at room temperature leads to a di-nuclear Cr(III)-Cr(III) complex, [Cr(BMO)2(OH)]2 (2). The complexes were characterized on the basis of their elemental analysis, Mass, IR, 1H and 13C-NMR and electronic spectra. The IR studies were useful in assigning the coordination mode of the benzilmonoxime ligand to the chromium(III) ion. In addition, the presence of a hydroxo bridge in the dimeric complex 2 is inferred from the IR spectral studies. The electronic spectra of the complexes revealed two bands due to d–d transitions, and one band assignable to an oxygen (pπ)→Cr(eg*) LMCT transition observed in both complexes. An additional charge transfer transition, assignable to μ-OH(pπ)→Cr(eg*), was only observed for the dimeric complex 2. The splitting energy and Racah parameter were calculated to be 18484 cm-1 and 560 cm-1 for [Cr(BMO)3] (1), 17986 cm-1 and 545 cm-1 for [Cr(BMO)2(OH)]2 (2) respectively." @default.
• W2150463313 created "2016-06-24" @default.
• W2150463313 creator A5074823156 @default.
• W2150463313 date "2011-02-01" @default.
• W2150463313 modified "2023-10-14" @default.
• W2150463313 title "Synthesis and Characterization of Two Novel Complexes of Cr(III) with Benzilmonoxime" @default.
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• W2150463313 doi "https://doi.org/10.1002/jccs.201190058" @default.
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