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- W2150489706 abstract "A series of novel two-dimensional (2D) lanthanide coordination polymers with 4-hydroxyquinoline-2-carboxylate (H2hqc) ligands, [Ln(Hhqc)3(H2O)]n·3nH2O (Ln = Eu (1), Tb (2), Sm (3), Nd (4), and Gd (5)) and [Ln(Hhqc)(ox)(H2O)2]n (Ln = Eu (6), Tb (7), Sm (8), Tm (9), Dy (10), Nd (11), Yb (12), and Gd (13); H2ox = oxalic acid), have been synthesized under hydrothermal conditions. Complexes 1–5 are isomorphous, which can be described as a two-dimensional (2D) hxl/Shubnikov network based on Ln2(CO2)4 paddle-wheel units, and the isomorphous complexes 6–13 feature a 2D decker layer architecture constructed by Ln-ox infinite chains cross-linked alternatively by bridging Hhqc– ligands. The room-temperature photoluminescence spectra of complexes EuIII (1 and 6), TbIII (2 and 7), and SmIII (3 and 8) exhibit strong characteristic emissions in the visible region, whereas NdIII (4 and 11) and YbIII (12) complexes display NIR luminescence upon irradiation at the ligand band. Moreover, the triplet state of H2hqc matches well with the emission level of EuIII, TbIII, and SmIII ions, which allows the preparation of new optical materials with enhanced luminescence properties." @default.
- W2150489706 created "2016-06-24" @default.
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- W2150489706 date "2012-12-03" @default.
- W2150489706 modified "2023-10-02" @default.
- W2150489706 title "Visible and NIR Photoluminescence Properties of a Series of Novel Lanthanide–Organic Coordination Polymers Based on Hydroxyquinoline–Carboxylate Ligands" @default.
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- W2150489706 doi "https://doi.org/10.1021/ic301261g" @default.
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