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- W2150541330 endingPage "4174" @default.
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- W2150541330 abstract "Abstract N ‐ Tosyl 3,3 ‐ dialkyl ‐ 2 ‐ ( tert ‐ butyldiphenylsilylmethyl)azetidines rearrange smoothly into the corresponding 2 ‐ alkenyl ‐ 3 ‐ ( tert ‐ butyldiphenylsilyl)amines upon exposure to BF 3 · OEt 2 in CH 2 Cl 2 . The reaction involves sequential σ C–N bond cleavage, 1,2 ‐ migration of the N ‐ tosyl‐aminomethyl group, and deprotonation of the resultant tert ‐ carbenium ions. For the instance in which the carbenium ion formed from migration of the N ‐ tosyl‐aminomethyl group is highly stable by virtue of being, for example, tertiary as well as benzylic, the migration takes place in sync with σ C–N bond cleavage, which leads to high configurational control at the tert ‐butyldiphenylsilylmethyl ‐ bearing carbon atom in the product." @default.
- W2150541330 created "2016-06-24" @default.
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- W2150541330 date "2013-05-15" @default.
- W2150541330 modified "2023-10-16" @default.
- W2150541330 title "A Route to 2-Alkenyl-3-(<i>tert</i>-butyldiphenylsilyl)amines and Application to the Construction of a Tricyclic Ring System" @default.
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- W2150541330 doi "https://doi.org/10.1002/ejoc.201300319" @default.
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