Matches in SemOpenAlex for { <https://semopenalex.org/work/W2150552994> ?p ?o ?g. }
- W2150552994 endingPage "7302" @default.
- W2150552994 startingPage "7299" @default.
- W2150552994 abstract "Abstract Asymmetric C(sp)C(sp 2 ) bond formation to give enantiomerically enriched 1,3‐butadienyl‐2‐carbinols occurred through a homoallenylboration reaction between a 2,3‐dienylboronic ester and aldehydes under the catalysis of a chiral phosphoric acid (CPA). A diverse range of enantiomerically enriched butadiene‐substituted secondary alcohols with aryl, heterocyclic, and aliphatic substituents were synthesized in very high yield with high enantioselectivity. Preliminary density functional theory (DFT) calculations suggest that the reaction proceeds via a cyclic six‐membered chairlike transition state with essential hydrogen‐bond activation in the allene reagent. The catalytic reaction was amenable to the gram‐scale synthesis of a chiral alkyl butadienyl adduct, which was converted into an interesting optically pure compound bearing a benzo‐fused spirocyclic cyclopentenone framework." @default.
- W2150552994 created "2016-06-24" @default.
- W2150552994 creator A5019165702 @default.
- W2150552994 creator A5024383687 @default.
- W2150552994 creator A5039352081 @default.
- W2150552994 creator A5064722135 @default.
- W2150552994 creator A5079533429 @default.
- W2150552994 creator A5082656751 @default.
- W2150552994 creator A5090577152 @default.
- W2150552994 date "2015-05-04" @default.
- W2150552994 modified "2023-10-18" @default.
- W2150552994 title "Asymmetric Synthesis of 1,3-Butadienyl-2-carbinols by the Homoallenylboration of Aldehydes with a Chiral Phosphoric Acid Catalyst" @default.
- W2150552994 cites W1963628009 @default.
- W2150552994 cites W1964819974 @default.
- W2150552994 cites W1970046945 @default.
- W2150552994 cites W1973599436 @default.
- W2150552994 cites W1974420174 @default.
- W2150552994 cites W1974955332 @default.
- W2150552994 cites W1981848710 @default.
- W2150552994 cites W2001074177 @default.
- W2150552994 cites W2003114412 @default.
- W2150552994 cites W2009253289 @default.
- W2150552994 cites W2010558976 @default.
- W2150552994 cites W2016075951 @default.
- W2150552994 cites W2016560868 @default.
- W2150552994 cites W2016846659 @default.
- W2150552994 cites W2032096252 @default.
- W2150552994 cites W2039190735 @default.
- W2150552994 cites W2039662507 @default.
- W2150552994 cites W2040383386 @default.
- W2150552994 cites W2043673215 @default.
- W2150552994 cites W2048828939 @default.
- W2150552994 cites W2058150889 @default.
- W2150552994 cites W2064535886 @default.
- W2150552994 cites W2065125806 @default.
- W2150552994 cites W2067442498 @default.
- W2150552994 cites W2067731984 @default.
- W2150552994 cites W2070025125 @default.
- W2150552994 cites W2085351645 @default.
- W2150552994 cites W2087825284 @default.
- W2150552994 cites W2098920213 @default.
- W2150552994 cites W2105571963 @default.
- W2150552994 cites W2114490864 @default.
- W2150552994 cites W2115007369 @default.
- W2150552994 cites W2121252264 @default.
- W2150552994 cites W2131762534 @default.
- W2150552994 cites W2140014401 @default.
- W2150552994 cites W2148331346 @default.
- W2150552994 cites W2161943614 @default.
- W2150552994 cites W2164146480 @default.
- W2150552994 cites W2169174125 @default.
- W2150552994 cites W2171345219 @default.
- W2150552994 cites W2312853724 @default.
- W2150552994 cites W2317081340 @default.
- W2150552994 cites W2319534265 @default.
- W2150552994 cites W2323205842 @default.
- W2150552994 cites W2331395706 @default.
- W2150552994 cites W2333000186 @default.
- W2150552994 cites W2950436633 @default.
- W2150552994 cites W2950576368 @default.
- W2150552994 cites W2950649878 @default.
- W2150552994 cites W2950764882 @default.
- W2150552994 cites W2950962160 @default.
- W2150552994 cites W2951676641 @default.
- W2150552994 cites W2951737607 @default.
- W2150552994 cites W4232877595 @default.
- W2150552994 cites W4235627433 @default.
- W2150552994 cites W4244331132 @default.
- W2150552994 cites W4245580571 @default.
- W2150552994 cites W4248140356 @default.
- W2150552994 cites W4248178114 @default.
- W2150552994 cites W4256024989 @default.
- W2150552994 cites W4376849756 @default.
- W2150552994 doi "https://doi.org/10.1002/anie.201501832" @default.
- W2150552994 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25939725" @default.
- W2150552994 hasPublicationYear "2015" @default.
- W2150552994 type Work @default.
- W2150552994 sameAs 2150552994 @default.
- W2150552994 citedByCount "48" @default.
- W2150552994 countsByYear W21505529942015 @default.
- W2150552994 countsByYear W21505529942016 @default.
- W2150552994 countsByYear W21505529942017 @default.
- W2150552994 countsByYear W21505529942018 @default.
- W2150552994 countsByYear W21505529942019 @default.
- W2150552994 countsByYear W21505529942020 @default.
- W2150552994 countsByYear W21505529942021 @default.
- W2150552994 countsByYear W21505529942022 @default.
- W2150552994 countsByYear W21505529942023 @default.
- W2150552994 crossrefType "journal-article" @default.
- W2150552994 hasAuthorship W2150552994A5019165702 @default.
- W2150552994 hasAuthorship W2150552994A5024383687 @default.
- W2150552994 hasAuthorship W2150552994A5039352081 @default.
- W2150552994 hasAuthorship W2150552994A5064722135 @default.
- W2150552994 hasAuthorship W2150552994A5079533429 @default.
- W2150552994 hasAuthorship W2150552994A5082656751 @default.
- W2150552994 hasAuthorship W2150552994A5090577152 @default.
- W2150552994 hasConcept C108204754 @default.
- W2150552994 hasConcept C134121241 @default.