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• W2150606751 abstract "Abstract The emission spectrum of the molecule OH (A 2 Σ→X 2 Π, 0–0) during a high-voltage, bi-directional pulsed corona discharge consisting of a gas mixture of N 2 and H 2 O in a wire-plate reactor has been successfully recorded under severe electromagnetic interference at atmospheric pressure. The relative vibrational populations and the vibrational temperature of N 2 (C, v ′) have also been determined. Due to the difficulty of determining the exact overlapping spectral line shape function of the OH (A 2 Σ→X 2 Π, 0–0) and the Δ v =+1 vibrational transition band of N 2 (C 3 Π u →B 3 Π g ), a practicable Gaussian form is used for calculating the emission intensity of OH (A 2 Σ→X 2 Π, 0-0) and the Δ v =+1 vibrational transition band of N 2 (C 3 Π u →B 3 Π g ). The emission intensity of OH (A 2 Σ→X 2 Π, 0–0) has been evaluated with a satisfactory accuracy by subtracting the emission intensity of the Δ v =+1 vibrational transition band of N 2 (C 3 Π u →B 3 Π g ) from the overlapping spectra. The relative population of OH (A 2 Σ) has been obtained by the emission intensity of OH (A 2 Σ→X 2 Π, 0–0) and Einstein's transition probability. The influences of peak voltage, pulse repetition rate and O 2 flow rate on the relative population of OH (A 2 Σ) radicals have also been investigated. We found that the relative population of OH (A 2 Σ) rises with an increase in both the peak applied voltage and the pulse repetition rate. When oxygen is added to an N 2 and H 2 O gas mixture, the relative population of OH (A 2 Σ) radicals decreases exponentially with an increase in added oxygen. The main physicochemical processes involved are also discussed in this paper." @default.
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• W2150606751 date "2007-06-01" @default.
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• W2150606751 title "Diagnosis of OH radical by optical emission spectroscopy in a wire-plate bi-directional pulsed corona discharge" @default.
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• W2150606751 doi "https://doi.org/10.1016/j.elstat.2006.10.007" @default.
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