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• W2150680531 endingPage "9975" @default.
• W2150680531 startingPage "9971" @default.
• W2150680531 abstract "The asymmetric synthesis of dragmacidin D (1) was completed in 10 steps. Its sole stereocenter was set by using direct asymmetric alkylation enabled by a C2-symmetric tetramine and lithium N-(trimethylsilyl)-tert-butylamide as the enolization reagent. A central Larock indole synthesis was employed in a convergent assembly of the heterocyclic subunits. The stereochemical evidence from this work strongly supports the predicted S configuration at the 6''' position, which is consistent with other members of the dragmacidin family of natural products." @default.
• W2150680531 created "2016-06-24" @default.
• W2150680531 creator A5026784477 @default.
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• W2150680531 date "2015-06-30" @default.
• W2150680531 modified "2023-10-11" @default.
• W2150680531 title "10‐Step Asymmetric Total Synthesis and Stereochemical Elucidation of (+)‐Dragmacidin D" @default.
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• W2150680531 doi "https://doi.org/10.1002/anie.201504113" @default.
• W2150680531 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4532559" @default.
• W2150680531 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26130270" @default.
• W2150680531 hasPublicationYear "2015" @default.
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