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- W2150871077 abstract "Abstract By spectral and chromatographic studies, the chemo-, regio- and stereoselectivity of the reaction of 1,2-alkadienephosphonic esters with bromine has been investigated in details. All reaction products were isolated and identified as pure compounds. It has been established that the main reaction pathways — heterocyclisation or 2,3-addition — depend strongly on the degree of substitution at C-3 carbon atom. Unlike to analogous addition reactions with sulfenyl- or selenenylchloride no 1,2-adducts have been detected. It has been proved that the 2,3-addition is highly Z-stereoselective. The probable mechanism of the reaction has been discussed." @default.
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- W2150871077 date "2000-02-01" @default.
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- W2150871077 title "A STUDY OF THE REACTION ROUTES UPON BROMINATION OF 1,2-ALKADIENEPHOSPHONIC ESTERS BY SPECTRAL AND CHROMATOGRAPHIC METHODS" @default.
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- W2150871077 doi "https://doi.org/10.1080/10426500008040517" @default.
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