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• W2150871917 abstract "Three novel homoscorpionate ligands containing a tert-butyl group in the 4-position have been synthesized: hydrotris(4-tert-butylpyrazol-1-yl)borate (Tp4tBu), hydrotris(4-tert-butyl-3-p-tolylpyrazol-1-yl)borate (TpTol,4tBu), and hydrotris(4-tert-butyl-3-isopropylpyrazol-1-yl)borate (TpiPr,4tBu). The 4-tert-butyl group does not alter the coordination chemistry of the first two ligands, relative to their 4-H analogues, however, the coordination chemistry of the third ligand is dramatically changed, making it a “tetrahedral enforcer”. The complexes Co[Tp4tBu][TpNp] (1), Tl[TpTol,4tBu] (2), Rh[TpTol,4tBu](CO)2 (3), Co[TpiPr,4tBu]Cl (4), Co[TpiPr,4tBu]N3 (5) and Co[TpiPr,4tBu]NCS (6) have been structurally characterized. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
• W2150871917 created "2016-06-24" @default.
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• W2150871917 date "2003-08-01" @default.
• W2150871917 modified "2023-09-27" @default.
• W2150871917 title "Remote Rotamer Control: The Effect of a 4-tert-Butyl Group on the Coordination Chemistry of TpR Ligands" @default.
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• W2150871917 doi "https://doi.org/10.1002/ejic.200300005" @default.
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