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- W2151046689 abstract "Abstract A novel, bis(peptide) based molecular actuator ( 1 ) has been synthesized. It is demonstrated to undergo contraction and expansion controlled by the addition and removal of Cu 2+ ; this is demonstrated by the direct observation of a change in hydrodynamic properties by using sedimentation analysis and size exclusion chromatography. The molecule undergoes a large change in sedimentation coefficient, axial ratio, and size exclusion chromatography elution time when it binds copper. The demonstration of a controlled change in the mechanical properties of 1 make it a good starting point for the development of molecular devices that will harness changes in molecular shape and size to create molecular devices such as sensors or valves." @default.
- W2151046689 created "2016-06-24" @default.
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- W2151046689 date "2008-07-10" @default.
- W2151046689 modified "2023-10-18" @default.
- W2151046689 title "Observation of Contraction and Expansion in a Bis(peptide)-Based Mechanical Molecular Actuator" @default.
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- W2151046689 doi "https://doi.org/10.1002/chem.200701942" @default.
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