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- W2151140562 abstract "Abstract Polarized infrared reflectance spectra from single crystals of two organic charge-transfer salts PrPht(TCNQ) 2 and PrQuin(TCNQ) 2 (where TCNQ = tetracyano- p quinodimethane, PrPht = N -propylphtalazinium, PrQuin = N -propylquinoxalinium) are studied over the frequency range 400–7000 cm −1 at room temperature (in both compounds the TCNQ molecules are arranged to form linear stacks with the tetramer repeat unit). Kramers-Kronig analysis of the reflectance is used to determine the optical properties. Some vibrational lines related to the coupling of a g phonon modes of the TCNQ molecule with electrons are split. The origin of a g mode splitting is discussed. Moreover, the electronic spectra (up to 20 000 cm −1 ) are measured at room temperature using the KBr pellet technique. The charge-transfer bands in tetramerized TCNQ salts are analysed." @default.
- W2151140562 created "2016-06-24" @default.
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- W2151140562 date "1995-09-01" @default.
- W2151140562 modified "2023-10-02" @default.
- W2151140562 title "Infrared spectra of tetramerized organic semiconductors PrPht(TCNQ)2 and PrQuin(TCNQ)2 — the problem of ag phonon mode splitting" @default.
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- W2151140562 doi "https://doi.org/10.1016/0379-6779(95)03354-8" @default.
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