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- W2151208643 abstract "Reaction of allyl and benzyl Grignard regents with functionalized nitroalkanes affords nitrones in good yield. This process shows considerable chemoselectivity; carbonyl groups and other highly reactive electrophilic functions are unaffected by the reaction conditions (THF,-70 o C). A mixture of regiosomers 4 and 5 is usually obtained, and the product distribution depends on the nature of the alkyl framework. An intermediate 3 is postulated, and the isomeric pair of nitrones arises, very likely through a selective syn elimination" @default.
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- W2151208643 date "2010-08-20" @default.
- W2151208643 modified "2023-09-30" @default.
- W2151208643 title "ChemInform Abstract: Nitrones from Addition of Benzyl and Allyl Grignard Reagents to Alkyl Nitro Compounds: Chemo-, Regio-, and Stereoselectivity of the Reaction." @default.
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- W2151208643 doi "https://doi.org/10.1002/chin.199309048" @default.
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