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- W2151330703 abstract "Anionic polymerization of β-methoxypropionaldehyde (MPA) was carried out in tetrahydrofuran (THF) by using benzophenone–monolithium complex as an initiator. An equilibrium between polymerization and depolymerization was observed at a temperature range of −90 to −70°C. From the temperature dependence of the equilibrium monomer concentration, thermodynamic parameters for the polymerization of MPA in THF were evaluated as follows: ΔHss = −4.8 ± 0.2 kcal/mole, ΔHSS = −22.4 ± 1.3 cal/mole-deg, and (Tc)ss = −59°C. The thermodynamic change upon the conversion of liquid monomer to condensed polymer was computed from both the partial mixing energy of MPA with THF and the linear relationship between the equilibrium volume fraction of MPA monomer and that of the resulting polymer: ΔH1c = −4.7 ± 0.2 kcal/mole, ΔS1c = −19.5 ± 1.3 cal/mole-deg, and (Tc)1c = −35°C." @default.
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- W2151330703 date "1975-12-01" @default.
- W2151330703 modified "2023-10-16" @default.
- W2151330703 title "Equilibrium anionic polymerization of β-methoxypropionaldehyde" @default.
- W2151330703 doi "https://doi.org/10.1002/pol.1975.170131212" @default.
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