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- W2151402225 endingPage "1348" @default.
- W2151402225 startingPage "1336" @default.
- W2151402225 abstract "Aliphatic nitrocompounds add to nonactivated α,β-unsaturated δ-thiolactams leading to 4-nitroalkyl functionalized δ-thiolactams in good yields. The addition is a stereocontrolled process with respect to substituents at C-6, and takes place producing trans 4,6-disubstituted adducts in most cases. Ease of the addition has been studied in relation to the structure of the δ-thiolactam acceptors, within the FMO-theory. Comparative study with analogous δ-lactams has shown the advantages of α,β-unsaturated δ-thiolactams in Michael addition and indicated high prospects of these compounds in the synthesis of 4-functionalized piperidine derivatives." @default.
- W2151402225 created "2016-06-24" @default.
- W2151402225 creator A5046116390 @default.
- W2151402225 date "2009-02-01" @default.
- W2151402225 modified "2023-10-16" @default.
- W2151402225 title "Michael addition of nitroalkanes to nonactivated α,β-unsaturated δ-thiolactams: reactivity, diastereoselectivity, and comparison to α,β-unsaturated δ-lactams" @default.
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- W2151402225 doi "https://doi.org/10.1016/j.tet.2008.12.037" @default.
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