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- W2151436031 abstract "This article describes the synthesis of novel well defined polysaccharide–polymer bioconjugates. Alkyne-containing bioconjugates were prepared using Cu(I) catalyzed azide–alkyne [3 + 2] dipolar cycloaddition, i.e. ‘click’ chemistry between an alkyne functionalized low molecular weight heparin (LMWH) and α-azide functionalized stimuli-responsive copolymers synthesized by atom transfer radical polymerization using Activators Generated by Electron Transfer (AGET). The alkyne functionality was incorporated into the heparin by conducting a high yield amidation of the polysaccharide using 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride. The structure and composition of the novel bioconjugates were confirmed by FTIR, NMR and thermogravimetric analysis (TGA)." @default.
- W2151436031 created "2016-06-24" @default.
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- W2151436031 date "2013-01-01" @default.
- W2151436031 modified "2023-10-18" @default.
- W2151436031 title "Smart heparin-based bioconjugates synthesized by a combination of ATRP and click chemistry" @default.
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- W2151436031 doi "https://doi.org/10.1039/c3py00055a" @default.
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