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- W2151503804 abstract "Intramolecular Diels-Alder reactions of ester-linked 1,3,8-nonatrienes carrying a diphenylcyclopropyl substituent attached to C1 proceed with high levels of stereoselectivity. The stereochemical outcomes of these reactions are explained by reference to B3LYP/6-31G(d) transition structures. Experimentally, the diphenylcyclopropane rings remain intact through these IMDA reactions, notwithstanding their predicted extremely high degree of asynchronicity (the B3LYP-computed lengths in the IMDA transition structures differ by as much as 1.1 angstroms), providing support to the notion that these reactions are concerted processes." @default.
- W2151503804 created "2016-06-24" @default.
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- W2151503804 date "2007-01-01" @default.
- W2151503804 modified "2023-10-01" @default.
- W2151503804 title "Stereocontrol of intramolecular Diels–Alder reactions by an allylic diphenylcyclopropyl group" @default.
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- W2151503804 doi "https://doi.org/10.1039/b708324f" @default.
- W2151503804 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18019536" @default.
- W2151503804 hasPublicationYear "2007" @default.
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