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- W2151507772 abstract "Current research efforts are aimed at developing hybrid polymer-vertically aligned carbon nanotube (CNT)membranes that are breathable in their native state but become blocked upon exposure to low levels of chem.warfare agents (CWA). Our approach utilizes polymers formed by ring opening metathesis polymn. (ROMP) thathave a highly non-planar structure in their neutral resting state to retain the high moisture vapor transport rateof the CNT membranes. Upon reacting with CWAs, these polymers can ionize and planarize, assuming acationic, arom. structure. This π-stacking drives a gel collapse that will block the CNT pores. These types ofpolymers will be grafted from the membrane using surface initiated ROMP (SI-ROMP) on norbornene-substitutedsurfaces. In this approach, the surface will be functionalized with a reactive ruthenium catalyst, and subsequentaddn. of norbornene-based monomers will result in a functional polymer grown from the membrane surface. Itis envisioned that this hybrid material will be useful to protect soldiers from chem. and biol. threats." @default.
- W2151507772 created "2016-06-24" @default.
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- W2151507772 date "2015-08-01" @default.
- W2151507772 modified "2023-09-27" @default.
- W2151507772 title "Chemical threat responsive carbon nanotube membranes" @default.
- W2151507772 hasPublicationYear "2015" @default.
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