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- W2151547221 abstract "Diastereoselectivities of up to 93 : 7 are attained at a reaction temperature of 0 to 25°C when (S) or (R) amino acid ester hydrochlorides and formaldehyde (formation of a chiral Schiff base) are allowed to react with dienes. Cleavage of the chiral auxiliary group was successfully carried out for phenylglycine and serine derivatives. Thus, phenylglycine and cyclopentadiene afforded the bicyclic aza compound 1 in enantiomerically pure form, while isoprene and serine afforded the didehydropiperidine 2." @default.
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- W2151547221 date "1988-02-01" @default.
- W2151547221 modified "2023-10-14" @default.
- W2151547221 title "Amino Acid Methyl Esters as Chiral Auxiliaries in Aza-Diels-Alder Reactions in Aqueous Solution" @default.
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- W2151547221 doi "https://doi.org/10.1002/anie.198802741" @default.
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