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- W2151587648 abstract "The interaction between in situ evaporated aluminum and plyvinyl alcohol (PVA) polymer at 300 K was studied by XPS. The aluminum condenses on the PVA surface by a Volmer–Weber (clustering) mechanism; it takes about a 3.7 monolayer deposition to nucleate clusters sufficiently large to exhibit core binding energies characteristic of bulk metal. Changes in the lineshapes of the C 1s and O 1s peaks and the appearance of a shifted peak in the Al 2p region were interpreted in terms of Al interactions with the surface alcoholic group HCOH, resulting in the formation of an interfacial organometallic complex exhibiting a stoichiometry of 1:1:1.5 for Al, C and O. Polar angle-resolved XPS measurements and differences in the attenuation factors of the signals from the complex show that the Al is on top and is closer to the oxygen atoms." @default.
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- W2151587648 date "1990-09-01" @default.
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- W2151587648 title "XPS study of metal/polymer interaction: Evaporated aluminum on polyvinyl alcohol polymer" @default.
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- W2151587648 doi "https://doi.org/10.1002/sia.740150903" @default.
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