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• W2151640189 abstract "Like NHCs? Not quite: Cyclic (alkyl)(amino)carbenes (CAACs) are strong σ-donors and have steric environments that differ dramatically from those of bulky, electron-rich phosphines (A) and cyclic diaminocarbenes (B). These readily available carbenes are desirable ligands for catalysis, as illustrated by the first palladium-mediated α-arylation of ketones and aldehydes with non-activated aryl chlorides at ambient temperature." @default.
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• W2151640189 date "2005-09-05" @default.
• W2151640189 modified "2023-10-03" @default.
• W2151640189 title "Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference" @default.
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• W2151640189 doi "https://doi.org/10.1002/anie.200501841" @default.
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