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• W2151653478 startingPage "1623" @default.
• W2151653478 abstract "The cleavage of CO bonds in lignin model compounds without hydrogen was developed using the commercially available Pd/C. Hydrogen donor solvents are helpful for this reaction through transfer hydrogenation, but not necessary. A redox neutral process that utilizes the internal hydrogen source for the cleavage is also possible. An initial mechanistic study indicates that the β-benzylic-H atom in the substrate plays a critical role and that the present system undergoes a process different from previous reports." @default.
• W2151653478 created "2016-06-24" @default.
• W2151653478 creator A5005070123 @default.
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• W2151653478 date "2014-04-01" @default.
• W2151653478 modified "2023-10-09" @default.
• W2151653478 title "Lignol Cleavage by Pd/C Under Mild Conditions and Without Hydrogen: A Role for Benzylic CH Activation?" @default.
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• W2151653478 doi "https://doi.org/10.1002/cssc.201301253" @default.
• W2151653478 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24692272" @default.
• W2151653478 hasPublicationYear "2014" @default.
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