FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2151655595> ?p ?o ?g. }

• W2151655595 endingPage "260" @default.
• W2151655595 startingPage "223" @default.
• W2151655595 abstract "ABSTRACT A detailed thermochemical kinetic model consisting of 165 reversible reactions has been developed to describe catalyzed polymerization of methane under adiabatic conditions. The model, an extension of that previously proposed (Weissman and Benson, 1984, 1989), was tested against available experimental data for CH3C1 pyrolysis in the absence and presence of CH4 in the temperature range 1260-1310 K (Weissman and Benson, 1984). Predictions of major product yields are reasonable although predictive inadequacies are discussed. Product distributions in the CH4/CI2 reaction were studied as a function of inlet/mixing temperature (To = 750-900 K), reactor pressure (PR = 1.0 —5.0 atmospheres) and CH4:C1, mole ratio (1.0-2.0). Product distribution is shown to be a strong function of inlet temperature and reactanl mole ratio. Choice of these parameters define the “window” of accessible reaction conditions experimentally available for useful product formation. Commercially attractive C2 yields (C2 H 2, C2H4), with minimal soot formation (as identified by the yields of precursor molecules, styrene and naphthalene), are predicted under ideal conditions. On the basis of the proposed model, the simulations indicate in situ mixing of preheated CH4and CI2 feeds is required. The latter must be achieved on millisecond time-scales in order to provide a homogeneous mixture at the onset of reaction. Only limited homogeneous formation of high molecular weight products is predicted at the residence times and temperatures considered, suggesting that the significant yields of soot observed experimentally may be a consequence of heterogeneous and/or mixing effect contributions. The effects of the latter experimental “perturbations” on homogeneous product formation, neglected in the simulations which were conducted under “ideal” conditions, are considered in detail." @default.
• W2151655595 created "2016-06-24" @default.
• W2151655595 creator A5004977906 @default.
• W2151655595 creator A5007946691 @default.
• W2151655595 creator A5024990620 @default.
• W2151655595 creator A5077105502 @default.
• W2151655595 creator A5081122465 @default.
• W2151655595 date "1995-01-01" @default.
• W2151655595 modified "2023-10-02" @default.
• W2151655595 title "Kinetic Model for Formation of Aromatics in the High Temperature Chlorination of Methane1" @default.
• W2151655595 cites W1514369830 @default.
• W2151655595 cites W1963540781 @default.
• W2151655595 cites W1964242079 @default.
• W2151655595 cites W1965289053 @default.
• W2151655595 cites W1970185735 @default.
• W2151655595 cites W1974705036 @default.
• W2151655595 cites W1976123559 @default.
• W2151655595 cites W1976445040 @default.
• W2151655595 cites W1982300119 @default.
• W2151655595 cites W1984854323 @default.
• W2151655595 cites W1986579082 @default.
• W2151655595 cites W1987824383 @default.
• W2151655595 cites W1990108848 @default.
• W2151655595 cites W1990614529 @default.
• W2151655595 cites W1991629012 @default.
• W2151655595 cites W1997132366 @default.
• W2151655595 cites W1997667684 @default.
• W2151655595 cites W1999000724 @default.
• W2151655595 cites W2003795796 @default.
• W2151655595 cites W2004722588 @default.
• W2151655595 cites W2005282835 @default.
• W2151655595 cites W2006059496 @default.
• W2151655595 cites W2009013906 @default.
• W2151655595 cites W2011802819 @default.
• W2151655595 cites W2011818539 @default.
• W2151655595 cites W2013957547 @default.
• W2151655595 cites W2015495727 @default.
• W2151655595 cites W2021344081 @default.
• W2151655595 cites W2024534451 @default.
• W2151655595 cites W2026534636 @default.
• W2151655595 cites W2029869863 @default.
• W2151655595 cites W2033522396 @default.
• W2151655595 cites W2034831872 @default.
• W2151655595 cites W2037019860 @default.
• W2151655595 cites W2038992194 @default.
• W2151655595 cites W2041026130 @default.
• W2151655595 cites W2042030723 @default.
• W2151655595 cites W2043468962 @default.
• W2151655595 cites W2044498294 @default.
• W2151655595 cites W2045968198 @default.
• W2151655595 cites W2048191441 @default.
• W2151655595 cites W2048875874 @default.
• W2151655595 cites W2050570152 @default.
• W2151655595 cites W2052799256 @default.
• W2151655595 cites W2056474098 @default.
• W2151655595 cites W2057160256 @default.
• W2151655595 cites W2058338418 @default.
• W2151655595 cites W2060398542 @default.
• W2151655595 cites W2062835884 @default.
• W2151655595 cites W2068220576 @default.
• W2151655595 cites W2070133878 @default.
• W2151655595 cites W2076765200 @default.
• W2151655595 cites W2079100325 @default.
• W2151655595 cites W2079346743 @default.
• W2151655595 cites W2079875986 @default.
• W2151655595 cites W2083610975 @default.
• W2151655595 cites W2086074697 @default.
• W2151655595 cites W2087912135 @default.
• W2151655595 cites W2089831090 @default.
• W2151655595 cites W2091230576 @default.
• W2151655595 cites W2093253264 @default.
• W2151655595 cites W2095416067 @default.
• W2151655595 cites W2095529240 @default.
• W2151655595 cites W2097381369 @default.
• W2151655595 cites W2108946807 @default.
• W2151655595 cites W2126111554 @default.
• W2151655595 cites W2143069380 @default.
• W2151655595 cites W2163915409 @default.
• W2151655595 cites W2168767902 @default.
• W2151655595 cites W227070568 @default.
• W2151655595 cites W2322810686 @default.
• W2151655595 cites W2332220020 @default.
• W2151655595 cites W2949398391 @default.
• W2151655595 cites W2949997371 @default.
• W2151655595 cites W2950775916 @default.
• W2151655595 cites W2951182159 @default.
• W2151655595 cites W2952441558 @default.
• W2151655595 cites W324203819 @default.
• W2151655595 cites W4241144970 @default.
• W2151655595 cites W6292766 @default.
• W2151655595 cites W78813812 @default.
• W2151655595 doi "https://doi.org/10.1080/00102209508907807" @default.
• W2151655595 hasPublicationYear "1995" @default.
• W2151655595 type Work @default.
• W2151655595 sameAs 2151655595 @default.
• W2151655595 citedByCount "8" @default.
• W2151655595 countsByYear W21516555952022 @default.
• W2151655595 crossrefType "journal-article" @default.

• next