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• W2151881137 abstract "Interaction of [Ru(EDTAH)(H2O)] (1), MHL(H2O), with CO in aqueous solution was investigated by potentiometry, spectrophotometry and electrochemistry. Complex 1 reacted with CO in the pH range 2–3.5 to form the protonated and the normal carbonyl complexes, MHLCO (2) and MLCO (3), respectively (L = EDTA, HL = EDTAH). Complex 3 combined with 1 to form the μ-COμ-OH dimer, [ML(CO)(OH)ML] (4). The log of the stability constants, determined spectrophotometrically, for the formation of complexes 2, 3 and 4 at 25°C (μ = 0.1 M) are 2.4, 4.9 and 3.72, respectively. The kinetics of the formation of complexes 2–4 were studied spectrophotometrically. The complexes constitute the first series of ruthenium(III)—carbonyls in aqueous solution, by the direct interaction of a soluble aquo RuIII—EDTA complex with CO." @default.
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• W2151881137 date "1989-01-01" @default.
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• W2151881137 title "Equilibrium and kinetic studies of the interaction of [RuIII(EDTAH)(H2O)]with CO" @default.
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• W2151881137 doi "https://doi.org/10.1016/s0277-5387(00)80357-5" @default.
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