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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2152050003> ?p ?o ?g. }

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• W2152050003 abstract "Abstract The negative charge originating from deprotonation of the methyl group is distributed over the 2‐picolyl ring. Bonding properties derived from the electron density distribution support the enamide character of picolyllithium (PicLi; the picture shows the deformation density of [2‐PicLi⋅PicH] 2 ), but electrophilic attack occurs at the deprotonated C atom. This reactivity is rationalized by the electrostatic potential, which guides electrophiles towards the nucleophilic C atom. magnified image" @default.
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• W2152050003 date "2009-03-30" @default.
• W2152050003 modified "2023-10-18" @default.
• W2152050003 title "Carbanion or Amide? First Charge Density Study of Parent 2-Picolyllithium" @default.
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• W2152050003 doi "https://doi.org/10.1002/anie.200806221" @default.
• W2152050003 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19288503" @default.
• W2152050003 hasPublicationYear "2009" @default.
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