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- W2152100056 endingPage "11773" @default.
- W2152100056 startingPage "11768" @default.
- W2152100056 abstract "In this work, we thoroughly investigated the effect of structural differentiation of a series of N,N-disubstituted chiral diamine ligands on the catalytic asymmetric aldol reactions between trifluoromethyl ketones and linear aliphatic ketones for the construction of chiral trifluoromethyl tertiary alcohols. A highly efficient primary-tertiary diamine ligand derived from (1R,2R)-1,2-diphenylethylenediamine was developed, which catalyzed the reactions with up to 99% yield and up to 94% enantioselectivity in the presence of p-toluenesulfonic acid (TsOH) using toluene as solvent." @default.
- W2152100056 created "2016-06-24" @default.
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- W2152100056 date "2014-11-18" @default.
- W2152100056 modified "2023-10-18" @default.
- W2152100056 title "Fine-Tuning the Structures of Chiral Diamine Ligands in the Catalytic Asymmetric Aldol Reactions of Trifluoromethyl Aromatic Ketones with Linear Aliphatic Ketones" @default.
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- W2152100056 doi "https://doi.org/10.1021/jo5022103" @default.
- W2152100056 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25390857" @default.
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