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• W2152132423 abstract "Abstract Reactions of CrCl 3 (thf) 3 with bis(imino)pyridines gave a series of {bis(imino)pyridine}chromium(III) trichloride complexes, {2,6‐(RNCMe) 2 C 5 H 3 N}CrCl 3 [R = C 6 H Pr 2 ‐2,6 ( 1 ), C 6 H 3 Et 2 ‐2,6 ( 2 ), C 6 H 3 Me 2 ‐2,6 ( 3 ), C 6 H 2 Me 3 ‐2,4,6 ( 4 ), C 6 H 3 Me 2 ‐3,5 ( 5 ), C 6 H 5 ( 6 ), cyclohexyl ( 7 ), 2‐methyl‐1‐naphthyl ( 8 ), C 6 H 3 F 2 ‐2,6 ( 9 ), C 6 H 3 Br 2 ‐2,6 ( 10 ), C 6 F 5 ( 11 )]. Pseudo‐octahedral geometries of 6 , 10 , and 11 were revealed by X‐ray crystallography. The complexes having bulky substituents such as 1 – 4 showed high activity for ethylene polymerization in combination with modified methylaluminoxane (MMAO) to give linear polyethylenes. In sharp contrast, the pentafluorophenyl complex 11 /modified methylaluminoxane system was found to be moderately active for ethylene homopolymerization to give moderately branched polyethylene with only ethyl branches. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3368–3375, 2005" @default.
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• W2152132423 date "2005-06-20" @default.
• W2152132423 modified "2023-10-10" @default.
• W2152132423 title "Unique catalytic behavior of chromium complexes having halogenated bis(imino)pyridine ligands for ethylene polymerization" @default.
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• W2152132423 doi "https://doi.org/10.1002/pola.20767" @default.
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