FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2152307173> ?p ?o ?g. }

• W2152307173 endingPage "569" @default.
• W2152307173 startingPage "561" @default.
• W2152307173 abstract "In this article we report the preparation and characterization of a peptide-based hydrogel, which possesses characteristic rheological properties, is pH responsive and can be functionalized at its thiol function. The tripeptide N-(fluorenyl-9-methoxycarbonyl)-L-Cys(acetamidomethyl)-L-His-L-Cys-OH 1 forms stable supramolecular aggregates in water leading to hydrogels above 1.5 wt%. Rheological analysis of the hydrogel revealed visco-elastic and shear thinning properties of samples containing 1.5 wt% of peptide 1. The hydrogel reversibly responds to pH changes. Below and above pH 6, electrostatic repulsion of the peptide results in a weakening of the three-dimensional gel network. Based on atomic force microscopy, small angle X-ray scattering and molecular dynamics simulations, it is proposed that the peptide assembles into nanostructures that tend to entangle at higher concentrations in water. The development of functional materials based on the peptide assemblies was possible via thiol-ene-click chemistry of the free thiol function at the C-terminal cysteine unit. As a proof of concept, the functionalization with adamantyl units to give 1-Ad was shown by molecular recognition of β-cyclodextrin vesicles. These vesicles were used as supramolecular cross-linkers of the assemblies of peptide 1 mixed with peptide 1-Ad leading to gel networks at a reduced peptide concentration." @default.
• W2152307173 created "2016-06-24" @default.
• W2152307173 creator A5000919967 @default.
• W2152307173 creator A5057878268 @default.
• W2152307173 creator A5066929221 @default.
• W2152307173 creator A5070451726 @default.
• W2152307173 creator A5087287749 @default.
• W2152307173 creator A5087994518 @default.
• W2152307173 date "2015-01-01" @default.
• W2152307173 modified "2023-10-16" @default.
• W2152307173 title "pH response and molecular recognition in a low molecular weight peptide hydrogel" @default.
• W2152307173 cites W1963613298 @default.
• W2152307173 cites W1974362310 @default.
• W2152307173 cites W1986316488 @default.
• W2152307173 cites W1990332976 @default.
• W2152307173 cites W1991281527 @default.
• W2152307173 cites W1993237312 @default.
• W2152307173 cites W1994486848 @default.
• W2152307173 cites W1997245260 @default.
• W2152307173 cites W2001606400 @default.
• W2152307173 cites W2003049596 @default.
• W2152307173 cites W2007499283 @default.
• W2152307173 cites W2008207378 @default.
• W2152307173 cites W2012325264 @default.
• W2152307173 cites W2015889028 @default.
• W2152307173 cites W2032084435 @default.
• W2152307173 cites W2037918016 @default.
• W2152307173 cites W2040764069 @default.
• W2152307173 cites W2047515399 @default.
• W2152307173 cites W2047726172 @default.
• W2152307173 cites W2051727755 @default.
• W2152307173 cites W2052634368 @default.
• W2152307173 cites W2064262168 @default.
• W2152307173 cites W2067258309 @default.
• W2152307173 cites W2068350472 @default.
• W2152307173 cites W2070826948 @default.
• W2152307173 cites W2084188261 @default.
• W2152307173 cites W2086756063 @default.
• W2152307173 cites W2087096980 @default.
• W2152307173 cites W2087903352 @default.
• W2152307173 cites W2088265640 @default.
• W2152307173 cites W2089529990 @default.
• W2152307173 cites W2089553410 @default.
• W2152307173 cites W2095130441 @default.
• W2152307173 cites W2096000959 @default.
• W2152307173 cites W2096239455 @default.
• W2152307173 cites W2101904711 @default.
• W2152307173 cites W2102847850 @default.
• W2152307173 cites W2125521662 @default.
• W2152307173 cites W2140714507 @default.
• W2152307173 cites W2162166182 @default.
• W2152307173 cites W2163505044 @default.
• W2152307173 cites W2164742553 @default.
• W2152307173 cites W2323570170 @default.
• W2152307173 cites W2331882689 @default.
• W2152307173 cites W2335729371 @default.
• W2152307173 cites W4237976776 @default.
• W2152307173 cites W4239858085 @default.
• W2152307173 doi "https://doi.org/10.1039/c4ob02069c" @default.
• W2152307173 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25379633" @default.
• W2152307173 hasPublicationYear "2015" @default.
• W2152307173 type Work @default.
• W2152307173 sameAs 2152307173 @default.
• W2152307173 citedByCount "32" @default.
• W2152307173 countsByYear W21523071732015 @default.
• W2152307173 countsByYear W21523071732016 @default.
• W2152307173 countsByYear W21523071732017 @default.
• W2152307173 countsByYear W21523071732018 @default.
• W2152307173 countsByYear W21523071732019 @default.
• W2152307173 countsByYear W21523071732020 @default.
• W2152307173 countsByYear W21523071732021 @default.
• W2152307173 countsByYear W21523071732022 @default.
• W2152307173 countsByYear W21523071732023 @default.
• W2152307173 crossrefType "journal-article" @default.
• W2152307173 hasAuthorship W2152307173A5000919967 @default.
• W2152307173 hasAuthorship W2152307173A5057878268 @default.
• W2152307173 hasAuthorship W2152307173A5066929221 @default.
• W2152307173 hasAuthorship W2152307173A5070451726 @default.
• W2152307173 hasAuthorship W2152307173A5087287749 @default.
• W2152307173 hasAuthorship W2152307173A5087994518 @default.
• W2152307173 hasBestOaLocation W21523071731 @default.
• W2152307173 hasConcept C108586683 @default.
• W2152307173 hasConcept C12554922 @default.
• W2152307173 hasConcept C130316041 @default.
• W2152307173 hasConcept C159985019 @default.
• W2152307173 hasConcept C167392928 @default.
• W2152307173 hasConcept C178790620 @default.
• W2152307173 hasConcept C181199279 @default.
• W2152307173 hasConcept C185592680 @default.
• W2152307173 hasConcept C188027245 @default.
• W2152307173 hasConcept C192562407 @default.
• W2152307173 hasConcept C200990466 @default.
• W2152307173 hasConcept C2779201268 @default.
• W2152307173 hasConcept C2779281246 @default.
• W2152307173 hasConcept C2781324293 @default.
• W2152307173 hasConcept C32909587 @default.
• W2152307173 hasConcept C34123561 @default.
• W2152307173 hasConcept C41625074 @default.

• next