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- W2152376530 abstract "In the present investigation, we have measured the secondary deuterium isotope effects in borohydride addition reaction for a serie of cyclohexanones, both hindered and unhindered. We observed an inverse isotope effect, kH/kD < 1.00 for those ketones; these inversions of the isotope effects are discussed in terms of torsional effects and hyperconjugative factor." @default.
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- W2152376530 date "2010-09-02" @default.
- W2152376530 modified "2023-09-26" @default.
- W2152376530 title "Réactions d'addition nucléophile sur les cétones dépendence conformationnelle de l'effet isotopique" @default.
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- W2152376530 doi "https://doi.org/10.1002/recl.19851040902" @default.
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