Matches in SemOpenAlex for { <https://semopenalex.org/work/W2152495547> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2152495547 endingPage "1237" @default.
- W2152495547 startingPage "1219" @default.
- W2152495547 abstract "Abstract General methods for the preparation of tetradentate ligands of the type HSCH2CONHRNCH(2-C6H4OH), H3LR, where R = (CH2)2, (CH2)3 and (CH2)4, are described. These ligands have been allowed to react with [Bu4N][TcOCl4] in methanol and the ligand-exchange reaction occurred only for the case where R=:(CH2)2 to give a penta-coordinated complex, TcOL(CH2)2. The reactions of H3LR with MO2(py)4Cl (M=Tc and Re) and ReO(PPh3)2cl3 in methanol yielded penta-coordinated complexes, MOL(CH2)2 (M=Tc and Re) and hexa-coordinated complexes, MOYLR [M=Tc and Re, Y=py, R=(CH2)3 and (CH2)4; M=Re, Y=PPh3, R=(CH2)2, (CH2)3 and (CH2)4]. ReO(PPh3)L(CH2)2 was converted quantitatively to ReOL(CH2)2 either during purification by column chromatography or in the presence of pyridine. While all efforts to add pyridine to MOL(CH2)2 (M=Tc and Re) failed, the reactions of ReO(PPh3)LR [R=(CH2)3 and (CH2)4] with pyridine in chloroform afforded ReO(py)LR. All complexes are neutral and air stable and were characterized by the usual measurements." @default.
- W2152495547 created "2016-06-24" @default.
- W2152495547 creator A5033733046 @default.
- W2152495547 creator A5058902431 @default.
- W2152495547 date "1995-10-01" @default.
- W2152495547 modified "2023-09-27" @default.
- W2152495547 title "Neutral Technetium(V) and Rhenium(V) Complexes with Tetradentate Ligands Containing N2OS Donor Sets" @default.
- W2152495547 cites W1505181903 @default.
- W2152495547 cites W1977741290 @default.
- W2152495547 cites W1986319215 @default.
- W2152495547 cites W1989825931 @default.
- W2152495547 cites W1992888689 @default.
- W2152495547 cites W1996855730 @default.
- W2152495547 cites W1997608540 @default.
- W2152495547 cites W1998722626 @default.
- W2152495547 cites W2067594619 @default.
- W2152495547 cites W2084478383 @default.
- W2152495547 cites W2090726870 @default.
- W2152495547 cites W2095302329 @default.
- W2152495547 cites W2115682547 @default.
- W2152495547 cites W2158124545 @default.
- W2152495547 cites W3138012732 @default.
- W2152495547 doi "https://doi.org/10.1080/15533179508014670" @default.
- W2152495547 hasPublicationYear "1995" @default.
- W2152495547 type Work @default.
- W2152495547 sameAs 2152495547 @default.
- W2152495547 citedByCount "3" @default.
- W2152495547 crossrefType "journal-article" @default.
- W2152495547 hasAuthorship W2152495547A5033733046 @default.
- W2152495547 hasAuthorship W2152495547A5058902431 @default.
- W2152495547 hasConcept C116569031 @default.
- W2152495547 hasConcept C13965031 @default.
- W2152495547 hasConcept C155647269 @default.
- W2152495547 hasConcept C170493617 @default.
- W2152495547 hasConcept C178790620 @default.
- W2152495547 hasConcept C179104552 @default.
- W2152495547 hasConcept C185592680 @default.
- W2152495547 hasConcept C2779485729 @default.
- W2152495547 hasConcept C2779607525 @default.
- W2152495547 hasConcept C2781144210 @default.
- W2152495547 hasConcept C505216180 @default.
- W2152495547 hasConcept C522557706 @default.
- W2152495547 hasConcept C55493867 @default.
- W2152495547 hasConcept C71240020 @default.
- W2152495547 hasConceptScore W2152495547C116569031 @default.
- W2152495547 hasConceptScore W2152495547C13965031 @default.
- W2152495547 hasConceptScore W2152495547C155647269 @default.
- W2152495547 hasConceptScore W2152495547C170493617 @default.
- W2152495547 hasConceptScore W2152495547C178790620 @default.
- W2152495547 hasConceptScore W2152495547C179104552 @default.
- W2152495547 hasConceptScore W2152495547C185592680 @default.
- W2152495547 hasConceptScore W2152495547C2779485729 @default.
- W2152495547 hasConceptScore W2152495547C2779607525 @default.
- W2152495547 hasConceptScore W2152495547C2781144210 @default.
- W2152495547 hasConceptScore W2152495547C505216180 @default.
- W2152495547 hasConceptScore W2152495547C522557706 @default.
- W2152495547 hasConceptScore W2152495547C55493867 @default.
- W2152495547 hasConceptScore W2152495547C71240020 @default.
- W2152495547 hasIssue "8" @default.
- W2152495547 hasLocation W21524955471 @default.
- W2152495547 hasOpenAccess W2152495547 @default.
- W2152495547 hasPrimaryLocation W21524955471 @default.
- W2152495547 hasRelatedWork W1736486341 @default.
- W2152495547 hasRelatedWork W1973056602 @default.
- W2152495547 hasRelatedWork W2053204670 @default.
- W2152495547 hasRelatedWork W2076309552 @default.
- W2152495547 hasRelatedWork W2082253980 @default.
- W2152495547 hasRelatedWork W2089281596 @default.
- W2152495547 hasRelatedWork W2152495547 @default.
- W2152495547 hasRelatedWork W2339111910 @default.
- W2152495547 hasRelatedWork W2952946256 @default.
- W2152495547 hasRelatedWork W3082109468 @default.
- W2152495547 hasVolume "25" @default.
- W2152495547 isParatext "false" @default.
- W2152495547 isRetracted "false" @default.
- W2152495547 magId "2152495547" @default.
- W2152495547 workType "article" @default.