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- W2152536633 abstract "Using selected theoretical methods the affinity of a large range of Lewis bases towards model cations has been quantified. The range of model cations includes the methyl cation as the smallest carbon-centered electrophile, the benzhydryl and trityl cations as models for electrophilic substrates encountered in Lewis base-catalyzed synthetic procedures, and the acetyl cation as a substrate model for acyl-transfer reactions. Affinities towards these cationic electrophiles are complemented by data for Lewis-base addition to Michael acceptors as prototypical neutral electrophiles." @default.
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- W2152536633 date "2012-08-31" @default.
- W2152536633 modified "2023-10-07" @default.
- W2152536633 title "Cation affinity numbers of Lewis bases" @default.
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- W2152536633 doi "https://doi.org/10.3762/bjoc.8.163" @default.
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