Matches in SemOpenAlex for { <https://semopenalex.org/work/W2152657181> ?p ?o ?g. }
- W2152657181 endingPage "3680" @default.
- W2152657181 startingPage "3673" @default.
- W2152657181 abstract "Abstract A high‐glass‐transition‐temperature polynorbornene, poly(NBEDPY), containing chromophore groups was synthesized by ring‐opening metathesis polymerization (ROMP) using Grubbs' catalysts; poly(HNBEDPY) was obtained by the reduction of poly(NBEDPY). The glass transition temperatures ( T g ) of poly(NBEDPY) and hydrogenated poly(HNBEDPY) were as high as 250 °C and 220 °C, respectively, because of the rigid dipyrene groups, which are higher than those of commercially available ring‐opened hydrogenated polynorbornenes (JSR ARTON®; 120–165 °C). The 10% weight‐loss temperatures of hydrogenated poly(HNBEDPY) and poly(NBEDPY) were up to 450 °C and 400 °C, respectively. A hydrogenated poly (HNBEDPY) film showed excellent transparency (over 91%). The photoluminescence emission spectra of poly(HNBEDPY) showed strong solvent‐polarity dependence, revealing that poly (HNBEDPY) underwent remarkable bathochromic shifts with an increase in solvent polarity. Poly(HNBEDPY) also showed remarkable fluorescent solvatochromism (blue in toluene, greenish yellow in dimethyl sulfoxide). The cyclic voltammogram of poly(HNBEDPY) film cast onto an indium tin oxide (ITO)‐coated glass substrate exhibited one reversible oxidation redox couple at 0.55 V versus Ag/Ag + in acetonitrile solution. The electrochromic characteristics of poly(HNBEDPY) showed reversibility, with a color change from its green neutral form to dark red upon the application of potentials from 0 to 1.0 V. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011" @default.
- W2152657181 created "2016-06-24" @default.
- W2152657181 creator A5011264032 @default.
- W2152657181 creator A5048641048 @default.
- W2152657181 creator A5050686209 @default.
- W2152657181 creator A5065312152 @default.
- W2152657181 creator A5067752162 @default.
- W2152657181 creator A5087400327 @default.
- W2152657181 date "2011-06-28" @default.
- W2152657181 modified "2023-10-18" @default.
- W2152657181 title "High glass transition and thermally stable polynorbornenes containing fluorescent dipyrene moieties via ring-opening metathesis polymerization" @default.
- W2152657181 cites W1529631183 @default.
- W2152657181 cites W1965305892 @default.
- W2152657181 cites W1967469150 @default.
- W2152657181 cites W1969256464 @default.
- W2152657181 cites W1969794339 @default.
- W2152657181 cites W1969907299 @default.
- W2152657181 cites W1971667451 @default.
- W2152657181 cites W1972115574 @default.
- W2152657181 cites W1978397510 @default.
- W2152657181 cites W1982820843 @default.
- W2152657181 cites W1983963673 @default.
- W2152657181 cites W1987493439 @default.
- W2152657181 cites W1987987831 @default.
- W2152657181 cites W1988008843 @default.
- W2152657181 cites W1989661152 @default.
- W2152657181 cites W1993095440 @default.
- W2152657181 cites W1993790948 @default.
- W2152657181 cites W1995420430 @default.
- W2152657181 cites W1997340579 @default.
- W2152657181 cites W1998788934 @default.
- W2152657181 cites W2009609657 @default.
- W2152657181 cites W2011861734 @default.
- W2152657181 cites W2015911592 @default.
- W2152657181 cites W2016665162 @default.
- W2152657181 cites W2018036503 @default.
- W2152657181 cites W2018567013 @default.
- W2152657181 cites W2019051833 @default.
- W2152657181 cites W2022613572 @default.
- W2152657181 cites W2025109945 @default.
- W2152657181 cites W2033813201 @default.
- W2152657181 cites W2047150205 @default.
- W2152657181 cites W2047785704 @default.
- W2152657181 cites W2048649024 @default.
- W2152657181 cites W2055603462 @default.
- W2152657181 cites W2055918789 @default.
- W2152657181 cites W2056993926 @default.
- W2152657181 cites W2057828433 @default.
- W2152657181 cites W2058214075 @default.
- W2152657181 cites W2059400698 @default.
- W2152657181 cites W2061837850 @default.
- W2152657181 cites W2064205409 @default.
- W2152657181 cites W2066780042 @default.
- W2152657181 cites W2069683509 @default.
- W2152657181 cites W2073474068 @default.
- W2152657181 cites W2075249512 @default.
- W2152657181 cites W2079798470 @default.
- W2152657181 cites W2080879377 @default.
- W2152657181 cites W2081719721 @default.
- W2152657181 cites W2082229396 @default.
- W2152657181 cites W2086580730 @default.
- W2152657181 cites W2086950906 @default.
- W2152657181 cites W2090391132 @default.
- W2152657181 cites W2093109455 @default.
- W2152657181 cites W2093427937 @default.
- W2152657181 cites W2096920650 @default.
- W2152657181 cites W2102869850 @default.
- W2152657181 cites W2102992896 @default.
- W2152657181 cites W2125797358 @default.
- W2152657181 cites W2141272103 @default.
- W2152657181 cites W2149648275 @default.
- W2152657181 cites W2149798336 @default.
- W2152657181 cites W2151090631 @default.
- W2152657181 cites W2154791869 @default.
- W2152657181 cites W2156449882 @default.
- W2152657181 cites W2952848839 @default.
- W2152657181 cites W98805693 @default.
- W2152657181 cites W2080400827 @default.
- W2152657181 doi "https://doi.org/10.1002/pola.24796" @default.
- W2152657181 hasPublicationYear "2011" @default.
- W2152657181 type Work @default.
- W2152657181 sameAs 2152657181 @default.
- W2152657181 citedByCount "12" @default.
- W2152657181 countsByYear W21526571812012 @default.
- W2152657181 countsByYear W21526571812013 @default.
- W2152657181 countsByYear W21526571812014 @default.
- W2152657181 countsByYear W21526571812015 @default.
- W2152657181 countsByYear W21526571812016 @default.
- W2152657181 countsByYear W21526571812021 @default.
- W2152657181 countsByYear W21526571812022 @default.
- W2152657181 crossrefType "journal-article" @default.
- W2152657181 hasAuthorship W2152657181A5011264032 @default.
- W2152657181 hasAuthorship W2152657181A5048641048 @default.
- W2152657181 hasAuthorship W2152657181A5050686209 @default.
- W2152657181 hasAuthorship W2152657181A5065312152 @default.
- W2152657181 hasAuthorship W2152657181A5067752162 @default.
- W2152657181 hasAuthorship W2152657181A5087400327 @default.
- W2152657181 hasConcept C101643646 @default.