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• W2152773964 abstract "Abstract The previously unknown crystal structure of mckinstryite, originally described as Ag 1.18 Cu 0.82 S or (Ag,Cu) 2 S, was solved and refined using single-crystal X-ray diffractometer data collected from a sample from the Clara mine, Black Forest (Mo- K α radiation, CCD area detector, R 1( F ) = 3.85%). Mckinstryite has the refined formula Ag 4.92 Cu 3.08 S 4 or Ag 1.23 Cu 0.77 S (idealized Ag 5 Cu 3 S 4 or Ag 1.25 Cu 0.75 S) and crystallizes in space group Pnma (no. 62), with a = 14.047(3) Å, b = 7.805(2) Å , c = 15.691(3) Å, V = 1720.3(7) Å 3 , Z = 8. The structure contains five Ag, six Cu and eight S sites in the asymmetric unit. One of the Ag sites shows minor Cu-for-Ag substitution. The topology is based on flat, interrupted (010) layers of Cu and S atoms (all atoms on y = 0.25), in which the Cu atoms show triangular or two-coordination to S (interrupted {6,3} tiling). These layers alternate with uneven layers consisting of Ag atoms showing irregular three- to two-coordination to S. Some fairly short Ag–Cu contact distances (2.781–2.884 Å) strongly indicate that metal-metal interaction plays an important role in mckinstryite. The topology is related to that of stromeyerite (∼AgCuS) which contains complete flat layers of Cu atoms triangularly coordinated to S atoms, alternating with layers of loosely packed Ag atoms. A critical evaluation of literature data on the chemical composition and unit-cell parameters of mckinstryite confirms the presence of a small compositional range of mckinstryite which extends approximately from Ag 1.18 Cu 0.82 S to Ag 1.25 Cu 0.75 S, with the presently studied sample being fairly Agrich. The accurate limits of this range at ambient temperature are still to be determined." @default.
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• W2152773964 date "2010-02-01" @default.
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• W2152773964 title "The crystal structure and compositional range of mckinstryite" @default.
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• W2152773964 doi "https://doi.org/10.1180/minmag.2010.074.1.73" @default.
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