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- W2152796317 abstract "Abstract Novel self‐assembled nano/microstructured conducting PANICN was prepared by in situ intercalative emulsion polymerization of aniline in aqueous dispersion of clay using bifunctional amphiphilic dopant, 3‐pentadecyl phenol‐4‐sulphonic acid (PDPSA) derivable from renewable resource. X‐ray diffraction and scanning electron microscopy (SEM) studies revealed the formation of monolayer of protonated PANI intercalated nanoclays with template polymerized self‐assembled micro/nanostructured protonated PANI. Nano/micro structured PANIs were formed by the supra molecular self‐assembling of the inter‐chain hydrogen bonding, inter‐plane phenyl stacking and electrostatic layer by layer self‐assembling (ELBS) between polarized alkyl chains present dopant anions and were manifested using fourier transform infra red spectroscopy and differential scanning calorimetry. On the basis of the results, structure‐directing effect of ‘anilinium salt micelle’ was schematically illustrated in this article. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2664–2673, 2007" @default.
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- W2152796317 date "2007-08-20" @default.
- W2152796317 modified "2023-10-09" @default.
- W2152796317 title "Facile green strategy for micro/nano structured conducting polyaniline-clay nanocomposite via template polymerization using amphiphilic dopant, 3-pentadecyl phenol 4-sulphonic acid" @default.
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- W2152796317 doi "https://doi.org/10.1002/polb.21273" @default.
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