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- W2152825329 abstract "Abstract Under certain conditions (150°C, P (C 2 H 4 )=1.4 MPa), the oligomerization of ethylene catalyzed by Cp 2 ZrCl 2 /EAO (ethylaluminoxane), Et 3 Al or (i-Bu) 3 Al afforded methylenecyclopentane (MCP) along with chain oligomers. The nature of cocatalysts and the Al/Zr ratios as well as the hydrolysis extent of Et 3 Al have tangible effects on the selectivity of the cyclic oligomer. With Et 3 Al as cocatalyst under optimal conditions, the oligomerization of ethylene gave MCP and C 4 –C 10 chain olefins in a ratio of 45/55. Download full-size image" @default.
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- W2152825329 date "2000-10-01" @default.
- W2152825329 modified "2023-09-27" @default.
- W2152825329 title "The effect of cocatalysts on the oligomerization and cyclization of ethylene catalyzed by zirconocene complexes" @default.
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- W2152825329 doi "https://doi.org/10.1016/s1381-1169(00)00313-7" @default.
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