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- W2152865912 abstract "Reaction of the imidotitanium complexes [Ti(NtBu)(N2Npy)(py)] (1) and [Ti(N-2,6-C6H3iPr2)(N2Npy)(py)] (2) with phenyl acetylene and tolyl acetylene in toluene gave the corresponding {2+2} cycloaddition products [Ti(N2Npy){κ2-N(tBu)CHCR}] (R = Ph: 3, Tol: 4) and [Ti(N2Npy){κ2-N(2,6-C6H3iPr2)CHCR}] (R = Ph: 5, Tol: 6). Complex 6 is the first example of a key intermediate in the anti-Markovnikov addition of a primary amine to a terminal acetylene which has been structurally characterized by X-ray diffraction." @default.
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- W2152865912 date "2004-01-01" @default.
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- W2152865912 title "Synthesis and structural characterization of an azatitanacyclobutene: the key intermediate in the catalytic anti-Markovnikov addition of primary amines to α-alkynes" @default.
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- W2152865912 doi "https://doi.org/10.1039/b316383k" @default.
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