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- W2152893266 abstract "In recent years, much attention is paid to the synthesis of hybrid antioxidants. In this respect the combination of alkyl phenol units with porphyrin macrocycle is rather promising.[1-5] Introduction of several sterically hindered phenol fragments to the periphery of the porphyrin macrocycle can lead to increased antioxidant activity, due to inhibition activity of phenolic moieties in respect to free radicals, and ability of the porphyrin itself to interact with free radicals and oxygen.[6-7] It is known that isobornylphenols possess membrane-protecting properties[8] and can be used as bioand technical antioxidants.[9] Therefore, the synthesis of porphyrin macrocycles with such substituents is of interest for the synthesis of hybrid antioxidants. In addition, isobornylphenols exhibit anti-inflammatory and hemorheological activity,[10-13] what allows to consider isobornylphenolic fragment as a potential pharmacophore group. In this regard, the introduction of these fragments to the periphery of the porphyrin macrocycle is promising in terms of obtaining new biologically active substances. Thus, the synthesis of hybrid molecules, containing porphyrin macrocycle and the fragments of terpenophenols, is of a great interest. Here we report on the synthesis of the first tetra(meso-aryl)porphyrin with isobornyl substituents in the aromatic rings by tetrapyrrole condensation of 4-hydroxy-3,5-diisobornylbenzaldehyde with pyrrole (Scheme 1)." @default.
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- W2152893266 date "2012-01-01" @default.
- W2152893266 modified "2023-10-14" @default.
- W2152893266 title "The First Tetra(meso-аryl)porphyrin with Isobornyl Substituents" @default.
- W2152893266 doi "https://doi.org/10.6060/mhc2012.120572b" @default.
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