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- W2152914318 abstract "The preparation and characterization of mononuclear complexes of the dinucleating 24-membered hexazadithiophenolate macrocycles H2L2 and H2L3 and their open-chain N3S2 analogues H2L4 and H2L5 are reported. The highly crystalline compounds [Ni(L4)] (4), [Ni(L5)] (5), [Co(L5)] (6), [NiH2(L2)]2+ (7), [ZnH2(L2)]2+ (8), and [NiH2(L3)]2+ (9) could be readily prepared by stoichiometric complexation reactions of the hydrochlorides of the free ligands with the corresponding metal(II) dichlorides and NEt3 in methanolic solution. All complexes were characterized by X-ray crystallography. Monometallic complexes 4–6 of the pentadentate ligands H2L4 and H2L5 feature distorted square pyramidal MN3S2 structures (τ = 0.01 to 0.44). Similar coordination geometries are observed for the macrocyclic complexes 7–9 of the octadentate ligands H2L2 and H2L3. The two hydrogen atoms in 7–9 are attached to the noncoordinating benzylic amine functions and are hydrogen bonded to the metal-bound thiophenolate functions. A comparison of the structures of 4–9 reveals that the macrocycles L2 and L3 have a rather flexible ligand backbone that do not confer unusual coordination geometries on the metal ions. We also report on the ability of the monometallic complexes 7 and 8 to serve as starting materials for the preparation of dinuclear complexes." @default.
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- W2152914318 date "2006-01-01" @default.
- W2152914318 modified "2023-10-10" @default.
- W2152914318 title "Preparation and characterization of mononuclear Co, Ni, and Zn complexes of dinucleating macrocyclic hexaaza-dithiophenolate ligands and their open-chain derivatives" @default.
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- W2152914318 doi "https://doi.org/10.1039/b603740b" @default.
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