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• W2152972241 abstract "[1] The solubility of hydrogen in Fe2O3-doped rutile and TiO2 (II) at 1100°C has been experimentally determined. H incorporation in rutile is coupled to substitution of Fe3+ onto the octahedral Ti4+ site. In contrast, TiO2 (II) contains no structurally-incorporated hydrogen. The dominant Fe3+ incorporation mechanism in both phases is unrelated to H content, and involves substitution of Fe3+ onto octahedral Ti4+ sites, charge-balanced by oxygen vacancies. Substitution of Fe2O3 into TiO2 (II) stabilizes the structure to much lower pressures than in the pure TiO2 system. Results indicate that Al-bearing stishovite could act as an important carrier of water in subducting oceanic crust, but that formation of the post-stishovite phase with the α-PbO2 structure would represent a significant dehydration event at the base of the lower mantle." @default.
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• W2152972241 date "2004-01-01" @default.
• W2152972241 modified "2023-10-16" @default.
• W2152972241 title "Solubility of hydrogen and ferric iron in rutile and TiO₂(II): Implications for phase assemblages during ultrahigh-pressure metamorphism and for the stability of silica polymorphs in the lower mantle" @default.
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• W2152972241 doi "https://doi.org/10.1029/2004gl019430" @default.
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