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- W2152994793 abstract "The glycosidation products of O-alpha-L-cinerulosyl-(1 leads to 4)-O-(3-O-acetyl-2-deoxy-alpha-L-fucosyl)-(1 leads to 4)-alpha, beta-L-rhodosamine with aklavinone, daunomycinone, adriamycinone and carminomycinone were synthesized and the resulting products were deacylated, yielding anthracyclines having the trisaccharide. We further synthesized N-monomethyl and N-didemethyl derivatives of daunomycinone trisaccharide by photolysis with sunlight. 3-O-Acyl derivatives of daunomycinone, carminomycinone and aklavinone glycosides showed a marked antitumor activity against L1210 leukemia in mice with ILS 110, 86 and 86%, respectively, while 3-O-acetyladriamycinone glycoside was highly toxic with a ILS of 44%." @default.
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- W2152994793 date "1982-01-01" @default.
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- W2152994793 title "Chemical modification of anthracycline antibiotics. IV. Synthesis of new anthracyclines with trisaccharide." @default.
- W2152994793 doi "https://doi.org/10.7164/antibiotics.35.312" @default.
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