FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2152996137> ?p ?o ?g. }

• W2152996137 endingPage "6340" @default.
• W2152996137 startingPage "6331" @default.
• W2152996137 abstract "The hydrothermal crystallization of ZnAPO-34 (CHA) molecular sieves has been studied for the first time using a combined in situ four technique setup utilizing SAXS/WAXS/XAFS/Raman to follow the various steps that occur during the complex transformation process of an amorphous precursor gel into a crystalline microporous material. These data are also supported by a detailed characterization of both the precursor gel (using Raman, NMR, XAFS, and TEM) and the final crystalline material (NMR, XRD, XAFS, TEM, and energy minimization calculations). Thus, all components during the various stages of reaction have been studied allowing for fundamental insight from the atomic/molecular level up to the bulk scale. On the basis of this multitechnique approach, the following observations are made: (i) The initial formation of a heterogeneous gel containing predominantly separate Al−O−P and Zn−O−P containing species as well as the presence of particles with a broad size distribution were noted. (ii) During sample heating, the SAXS data reveal a second population (14−16 nm) at the onset of crystallization, which were also accompanied by changes in both the ZnO3−O−O3P environment (XAFS) and the template conformer state (Raman). (iii) Before crystallization, Zn2+ species appear heterogeneously distributed throughout the sample, but in the final crystalline CHA phase Zn2+, it is much more homogeneously distributed. One template molecule is found per CHA cage. (iv) Zn2+ is found to promote nano particle growth and that results in the production of increasing amounts of crystalline material. (v) The structure-directing effect of Zn2+ ions leading to CHA formation is most likely initiated via an electrostatic interaction between Zn2+ in a Zn−O−P−O−Al−O−P matrix and the TEA template." @default.
• W2152996137 created "2016-06-24" @default.
• W2152996137 creator A5010473096 @default.
• W2152996137 creator A5018029048 @default.
• W2152996137 creator A5035177225 @default.
• W2152996137 creator A5035457940 @default.
• W2152996137 creator A5044081062 @default.
• W2152996137 creator A5053188243 @default.
• W2152996137 creator A5053749887 @default.
• W2152996137 creator A5054964072 @default.
• W2152996137 creator A5056344298 @default.
• W2152996137 creator A5079749026 @default.
• W2152996137 creator A5080091504 @default.
• W2152996137 date "2011-03-07" @default.
• W2152996137 modified "2023-09-26" @default.
• W2152996137 title "Probing ZnAPO-34 Self-Assembly Using Simultaneous Multiple in Situ Techniques" @default.
• W2152996137 cites W1546033764 @default.
• W2152996137 cites W1591090301 @default.
• W2152996137 cites W1964925726 @default.
• W2152996137 cites W1965721735 @default.
• W2152996137 cites W1968617400 @default.
• W2152996137 cites W1969555886 @default.
• W2152996137 cites W1972528455 @default.
• W2152996137 cites W1974959322 @default.
• W2152996137 cites W1980161148 @default.
• W2152996137 cites W1985682531 @default.
• W2152996137 cites W1987364219 @default.
• W2152996137 cites W1988539238 @default.
• W2152996137 cites W1999293298 @default.
• W2152996137 cites W2001475122 @default.
• W2152996137 cites W2001665630 @default.
• W2152996137 cites W2002048824 @default.
• W2152996137 cites W2004671984 @default.
• W2152996137 cites W2005038347 @default.
• W2152996137 cites W2007385091 @default.
• W2152996137 cites W2007972181 @default.
• W2152996137 cites W2009839551 @default.
• W2152996137 cites W2012948478 @default.
• W2152996137 cites W2017984060 @default.
• W2152996137 cites W2023256250 @default.
• W2152996137 cites W2025689430 @default.
• W2152996137 cites W2026973795 @default.
• W2152996137 cites W2035176265 @default.
• W2152996137 cites W2041315714 @default.
• W2152996137 cites W2043887792 @default.
• W2152996137 cites W2046937773 @default.
• W2152996137 cites W2047431481 @default.
• W2152996137 cites W2048165587 @default.
• W2152996137 cites W2053872609 @default.
• W2152996137 cites W2057502998 @default.
• W2152996137 cites W2058385537 @default.
• W2152996137 cites W2063928677 @default.
• W2152996137 cites W2067537471 @default.
• W2152996137 cites W2070227796 @default.
• W2152996137 cites W2071645687 @default.
• W2152996137 cites W2072270478 @default.
• W2152996137 cites W2072976471 @default.
• W2152996137 cites W2087747981 @default.
• W2152996137 cites W2087821615 @default.
• W2152996137 cites W2088501464 @default.
• W2152996137 cites W2089604989 @default.
• W2152996137 cites W2089977079 @default.
• W2152996137 cites W2100528433 @default.
• W2152996137 cites W2101921595 @default.
• W2152996137 cites W2102957372 @default.
• W2152996137 cites W2111396745 @default.
• W2152996137 cites W2124655968 @default.
• W2152996137 cites W2140549170 @default.
• W2152996137 cites W2144374669 @default.
• W2152996137 cites W2146774107 @default.
• W2152996137 cites W2149952452 @default.
• W2152996137 cites W2157734189 @default.
• W2152996137 cites W2317465662 @default.
• W2152996137 cites W2775237778 @default.
• W2152996137 cites W2951388748 @default.
• W2152996137 cites W4256374228 @default.
• W2152996137 doi "https://doi.org/10.1021/jp200043b" @default.
• W2152996137 hasPublicationYear "2011" @default.
• W2152996137 type Work @default.
• W2152996137 sameAs 2152996137 @default.
• W2152996137 citedByCount "33" @default.
• W2152996137 countsByYear W21529961372012 @default.
• W2152996137 countsByYear W21529961372013 @default.
• W2152996137 countsByYear W21529961372014 @default.
• W2152996137 countsByYear W21529961372015 @default.
• W2152996137 countsByYear W21529961372016 @default.
• W2152996137 countsByYear W21529961372017 @default.
• W2152996137 countsByYear W21529961372018 @default.
• W2152996137 countsByYear W21529961372019 @default.
• W2152996137 countsByYear W21529961372020 @default.
• W2152996137 countsByYear W21529961372021 @default.
• W2152996137 countsByYear W21529961372022 @default.
• W2152996137 countsByYear W21529961372023 @default.
• W2152996137 crossrefType "journal-article" @default.
• W2152996137 hasAuthorship W2152996137A5010473096 @default.
• W2152996137 hasAuthorship W2152996137A5018029048 @default.
• W2152996137 hasAuthorship W2152996137A5035177225 @default.
• W2152996137 hasAuthorship W2152996137A5035457940 @default.

• next