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- W2153074311 abstract "We present the Raman spectrum of pure liquid D2O at −27.0°C, 17°C lower than any previously reported Raman spectrum of liquid D2O. The liquid's OD stretch band at −27.0°C displays a prominent feature which is clearly analogous to the ν1 in-phase mode in D2O ice Ih providing strong evidence that the structure of cold liquid D2O's OD band is principally due to strong intermolecular coupling. Deeply supercooled liquid D2O displays this ν1 in-phase feature more clearly than deeply supercooled liquid H2O due to the smaller disparity in the DO mass ratio compared to that of HO which enhances this coupling." @default.
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- W2153074311 date "1992-03-01" @default.
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- W2153074311 title "Evidence for the importance of intermolecular coupling in the OD band's vibrational structure in deeply supercooled liquid D2O" @default.
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- W2153074311 doi "https://doi.org/10.1016/0009-2614(92)85197-i" @default.
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