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• W2153114365 abstract "We herein report the synthesis of 3-fluoro-2-methylene-pyrrolidine (3a) and -piperidine (3b) from 1,5- and 1,6-aminoalkynes, respectively, using a combination of a gold-catalyzed hydroamination reaction followed by electrophilic trapping of an intermediate cyclic enamine by Selectfluor. Careful attention was paid to the elucidation of the mechanism and Selectfluor was suggested to play the double role of promoting the oxidation of gold(I) to a gold(III) active species and also the electrophilic fluorination of the enamine intermediates." @default.
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• W2153114365 date "2011-10-07" @default.
• W2153114365 modified "2023-09-24" @default.
• W2153114365 title "Combination of gold catalysis and Selectfluor for the synthesis of fluorinated nitrogen heterocycles" @default.
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• W2153114365 doi "https://doi.org/10.3762/bjoc.7.162" @default.
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