FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2153178286> ?p ?o ?g. }

• W2153178286 endingPage "1225" @default.
• W2153178286 startingPage "1217" @default.
• W2153178286 abstract "Sila[1]ferrocenophanes with multiple alkyne substituents [Fe(η-C5H4)2Si(C⋮CtBu)2] (2) and [Fe(η-C5H4)2Si(Me)C⋮CC⋮CPh] (5) have been synthesized and structurally characterized. These compounds are prepared by reacting [LiC⋮CtBu] or [LiC⋮CC⋮CPh] with sila[1]ferrocenophanes containing silicon−chlorine bonds. Ring-opening polymerizations (ROP) of 2 and 5 have been studied using transition metal-catalyzed, thermal, anionic, and photocontrolled routes. Thermal and anionic ROP both failed to give significant amounts of polymer (<30%). And unlike most other ferrocenophanes, 2 cannot be polymerized by Karstedt's catalyst, possibly due to chelation of the catalyst by the acetylide ligands. Platinum-catalyzed ROP of 5 was also relatively ineffective, giving polymers with bimodal molecular weight distributions in moderate yields. Nevertheless, living polymerization of 2 and 5 was possible using photocontrolled ROP with NaCp as initiator. The key to photocontrolled ROP was the reduced basicity of NaCp compared to BuLi..." @default.
• W2153178286 created "2016-06-24" @default.
• W2153178286 creator A5019368956 @default.
• W2153178286 creator A5076582889 @default.
• W2153178286 creator A5080321754 @default.
• W2153178286 date "2007-01-26" @default.
• W2153178286 modified "2023-09-26" @default.
• W2153178286 title "Synthesis, Characterization, and Photocontrolled Ring-Opening Polymerization of Sila[1]ferrocenophanes with Multiple Alkyne Substituents" @default.
• W2153178286 cites W1505503266 @default.
• W2153178286 cites W1563954963 @default.
• W2153178286 cites W1927849564 @default.
• W2153178286 cites W1960866743 @default.
• W2153178286 cites W1965459878 @default.
• W2153178286 cites W1974393194 @default.
• W2153178286 cites W1977228155 @default.
• W2153178286 cites W1986156493 @default.
• W2153178286 cites W1989676980 @default.
• W2153178286 cites W2000466466 @default.
• W2153178286 cites W2001338086 @default.
• W2153178286 cites W2002770471 @default.
• W2153178286 cites W2005658324 @default.
• W2153178286 cites W2008739116 @default.
• W2153178286 cites W2009093410 @default.
• W2153178286 cites W2047794238 @default.
• W2153178286 cites W2049709348 @default.
• W2153178286 cites W2065667361 @default.
• W2153178286 cites W2075442635 @default.
• W2153178286 cites W2077324189 @default.
• W2153178286 cites W2093077889 @default.
• W2153178286 cites W2094964152 @default.
• W2153178286 cites W2106510039 @default.
• W2153178286 cites W2169171285 @default.
• W2153178286 cites W2478416020 @default.
• W2153178286 cites W2950974896 @default.
• W2153178286 cites W2952139354 @default.
• W2153178286 doi "https://doi.org/10.1021/om0607671" @default.
• W2153178286 hasPublicationYear "2007" @default.
• W2153178286 type Work @default.
• W2153178286 sameAs 2153178286 @default.
• W2153178286 citedByCount "2" @default.
• W2153178286 countsByYear W21531782862012 @default.
• W2153178286 crossrefType "journal-article" @default.
• W2153178286 hasAuthorship W2153178286A5019368956 @default.
• W2153178286 hasAuthorship W2153178286A5076582889 @default.
• W2153178286 hasAuthorship W2153178286A5080321754 @default.
• W2153178286 hasConcept C106773901 @default.
• W2153178286 hasConcept C155647269 @default.
• W2153178286 hasConcept C161790260 @default.
• W2153178286 hasConcept C166940927 @default.
• W2153178286 hasConcept C178790620 @default.
• W2153178286 hasConcept C185592680 @default.
• W2153178286 hasConcept C188027245 @default.
• W2153178286 hasConcept C203897987 @default.
• W2153178286 hasConcept C2779012754 @default.
• W2153178286 hasConcept C2779627003 @default.
• W2153178286 hasConcept C2780378348 @default.
• W2153178286 hasConcept C44228677 @default.
• W2153178286 hasConcept C521977710 @default.
• W2153178286 hasConceptScore W2153178286C106773901 @default.
• W2153178286 hasConceptScore W2153178286C155647269 @default.
• W2153178286 hasConceptScore W2153178286C161790260 @default.
• W2153178286 hasConceptScore W2153178286C166940927 @default.
• W2153178286 hasConceptScore W2153178286C178790620 @default.
• W2153178286 hasConceptScore W2153178286C185592680 @default.
• W2153178286 hasConceptScore W2153178286C188027245 @default.
• W2153178286 hasConceptScore W2153178286C203897987 @default.
• W2153178286 hasConceptScore W2153178286C2779012754 @default.
• W2153178286 hasConceptScore W2153178286C2779627003 @default.
• W2153178286 hasConceptScore W2153178286C2780378348 @default.
• W2153178286 hasConceptScore W2153178286C44228677 @default.
• W2153178286 hasConceptScore W2153178286C521977710 @default.
• W2153178286 hasIssue "5" @default.
• W2153178286 hasLocation W21531782861 @default.
• W2153178286 hasOpenAccess W2153178286 @default.
• W2153178286 hasPrimaryLocation W21531782861 @default.
• W2153178286 hasRelatedWork W1960866743 @default.
• W2153178286 hasRelatedWork W1965459878 @default.
• W2153178286 hasRelatedWork W1980498246 @default.
• W2153178286 hasRelatedWork W1987756924 @default.
• W2153178286 hasRelatedWork W2001338086 @default.
• W2153178286 hasRelatedWork W2002770471 @default.
• W2153178286 hasRelatedWork W2004936784 @default.
• W2153178286 hasRelatedWork W2005240576 @default.
• W2153178286 hasRelatedWork W2009093410 @default.
• W2153178286 hasRelatedWork W2011071481 @default.
• W2153178286 hasRelatedWork W2045704941 @default.
• W2153178286 hasRelatedWork W2051310131 @default.
• W2153178286 hasRelatedWork W2057910263 @default.
• W2153178286 hasRelatedWork W2060292415 @default.
• W2153178286 hasRelatedWork W2068884517 @default.
• W2153178286 hasRelatedWork W2081139316 @default.
• W2153178286 hasRelatedWork W2088505722 @default.
• W2153178286 hasRelatedWork W2088506029 @default.
• W2153178286 hasRelatedWork W2101654608 @default.
• W2153178286 hasRelatedWork W2147901429 @default.
• W2153178286 hasVolume "26" @default.
• W2153178286 isParatext "false" @default.
• W2153178286 isRetracted "false" @default.

• next