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- W2153181620 abstract "An efficient catalytic method is described for the preparative conversion of hydroquinones to quinones with dioxygen under mild conditions. The use of the gaseous nitrogen oxide (NO x ) catalyst allows a simple workup procedure for the isolation of quinones in essentially quantitative yields by merely removing the low-boiling solvent dichloromethane in vacuo. The mechanism of the catalytic autoxidation of hydroquinones is ascribed to the critical role of nitrosonium (NO + ) in the one-electron oxidation of hydroquinone, followed by the reoxidation of the reduced nitric oxide (NO) with dioxygen. A extensive series of complex interchanges among various NO x species in nitrogen-(V),-(IV), -(III), and -(II) oxidation states, coupled with stepwise oxidation of hydroquinone via a successive series of one-electron/proton transfers, form the critical components of the catalytic cycle" @default.
- W2153181620 created "2016-06-24" @default.
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- W2153181620 date "2010-08-18" @default.
- W2153181620 modified "2023-09-26" @default.
- W2153181620 title "ChemInform Abstract: Novel Catalysis of Hydroquinone Autoxidation with Nitrogen Oxides." @default.
- W2153181620 cites W2952074442 @default.
- W2153181620 doi "https://doi.org/10.1002/chin.199444104" @default.
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