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- W2153236367 abstract "The 5, 8, 9, and 11 vertex deltahedra containing the minimum number of tetrahedral chambers are inherently fluxional since certain possible diamond-square-diamond rearrangements can lead directly to a polyhedron identical to the original one except for interchanges of some vertices. By this criterion the 6, 10, and 12 vertex deltahedra are inherently rigid. The 7 vertex pentagonal bipyramid is also inherently rigid but can stereochemically non-rigid in cases where a capped octahedron is an accessible intermediate. These topological observations are consistent with known information on the stereochemical non-rigidity and hydrolytic stability stability of the delta-hedral borane anions BnH2−n and the stereochemical non-rigidity of MLn coordination complexes. Thus the stereochemical non-rigidity of all ML7 complexes investigated as contrasted with the stereochemical rigidity of B7H2−7 can be related to the energetic accessibility of capped octahedral species in ML7 complexes but not in B7H2−7." @default.
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- W2153236367 date "1981-01-01" @default.
- W2153236367 modified "2023-10-03" @default.
- W2153236367 title "Chemical applications of topology and group theory. 11. Degenerate edges as a source of inherent fluxionality in deltahedra" @default.
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- W2153236367 doi "https://doi.org/10.1016/s0020-1693(00)90490-0" @default.
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