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- W2153293943 abstract "The electronic structure and orientation of tetratetracontane (n-C44H90, TTC) monolayer film on Cu(100) were studied by angle-resolved UPS (ARUPS). We observed a2 × 1 LEED pattern at room temperature. This indicates that the TTC molecule lies on the Cu(100) surface with its chain axis parallel to the Cu(110) direction. The application of the dipole selection rules to normal emission spectrum revealed that the C-C-C plane of TTC is parallel to the surface (flat-on orientation). We also examined the dependence of the photoemission spectra on the take off angle. The simulated spectra for flat-on orientation based on independent atomic center (IAC) approximation combined with ab initio MO calculations are in good agreement with the observed spectra. These results verify the deduced molecular orientation and demonstrate the reliability of theoretical simulation with IAC approximation." @default.
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- W2153293943 date "1998-03-01" @default.
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- W2153293943 title "Angle-resolved UPS study and simulation with IAC approximation for oriented monolayer of tetratetracontane (n-C44H90) on Cu(100)" @default.
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- W2153293943 doi "https://doi.org/10.1016/s0368-2048(97)00246-6" @default.
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