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- W2153320137 abstract "reatment of 3-tosyl-D-mannose-4,6-acetonide 9 with sodium borohydride affords an epoxy alcohol 11 which on treatment with base gives 1,5-anhydro-D-allitol-4,6-acetonide 15 by a 6-endo opening of the rearranged epoxy alcohol 13 rather than the product of a 5-exo opening, namely a C-ribose acetonide derivative 14." @default.
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- W2153320137 date "1991-10-01" @default.
- W2153320137 modified "2023-10-09" @default.
- W2153320137 title "Conversion of D-mannose into 1,5-anhydro-D-allitol-4,6-acetonide; unusual intramolecular epoxy alcohol opening in base" @default.
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- W2153320137 doi "https://doi.org/10.1016/0040-4039(91)80760-4" @default.
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