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• W2153403940 endingPage "1317" @default.
• W2153403940 startingPage "1308" @default.
• W2153403940 abstract "2,4,6-trichlorophenol (TCP) is oxidized by potassium monopersulfate or hydrogen peroxide in the presence of iron or manganese tetrasulfonatophthalocyanines (FePcS or MnPcS) to yield not only the corresponding 2,6-dichloro-1,4-benzoquinone but also ring-cleavage products. Catalytic oxidation of the TCP ring by hydrogen peroxide is more efficient than by potassium monopersulfate, despite a slower substrate conversion, suggesting that different mechanisms are involved for these two catalytic systems: a metal-oxo mechanism for FePcS/KHSO5 and a metal-peroxo mechanism for FePcS/H2O2. Eight different final oxidation products and four quinone intermediates have been identified in the oxidation of TCP by the FePcS/H2O2 catalytic system. Chloromaleic acid is the main product of the oxidative ring cleavage. An iron-peroxo complex PcS-FeOOH is probably the active species responsible for the epoxidation of 2,6-dichloro-1,4-benzoquinone and the C–C bond cleavage of 3,5-dichloro-2-hydroxy-1,4-benzoquinone ring, both intermediates generated during the catalytic TCP degradation. The oxidation of pentachlorophenol (PCP) is also catalyzed by FePcS or MnPcS with KHSO5 or H2O2." @default.
• W2153403940 created "2016-06-24" @default.
• W2153403940 creator A5038194956 @default.
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• W2153403940 date "1996-10-01" @default.
• W2153403940 modified "2023-10-08" @default.
• W2153403940 title "Oxidative Degradation of Polychlorinated Phenols Catalyzed by Metallosulfophthalocyanines" @default.
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• W2153403940 doi "https://doi.org/10.1002/chem.19960021019" @default.
• W2153403940 hasPublicationYear "1996" @default.
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