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W2153453531 abstract "Cationic nickel(II) complexes containing chelating O,O′-donor maltolate or ethyl maltolate ligands in conjunction with bidentate bisphosphine ligands Ph2P(CH2) n PPh2 were prepared by a one-pot reaction starting from nickel(II) acetate, bisphosphine, maltol (or ethyl maltol), and trimethylamine, and isolated as their tetraphenylborate salts. An X-ray structure determination of [Ni(maltolate)(Ph2PCH2CH2PPh2)]BPh4 shows that the maltolate ligand binds asymmetrically to the (slightly distorted) square-planar nickel(II) center. The simplicity of the synthetic method was extended to the synthesis of the known platinum(II) maltolate complex [Pt(maltolate)(PPh3)2]BPh4 which was obtained in high purity." @default.
W2153453531 created "2016-06-24" @default.
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W2153453531 date "2011-02-02" @default.
W2153453531 modified "2023-09-27" @default.
W2153453531 title "Synthesis and characterization of nickel(II) maltolate complexes containing ancillary bisphosphine ligands" @default.
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W2153453531 doi "https://doi.org/10.1080/00958972.2011.553224" @default.
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